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Bredereck's Reagent bis(dimethylamino)(tert-butoxy)methane CAS: 5815-08-7
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Name: Bis(dimethylamino)(tert-butoxy)methane
Other name: Bredereck's Reagent;
N,N,N',N'-Tetramethyl(tert-butoxy)methanediamine; 1-(tert-Butoxy)-N,N,N',N'-tetramethylmethanediamine
CAS: 5815-08-7
EINECS: 227-383-9
MF: C9H22N2O
MW: 174.28
Density: 0.844g/mL
Purity: 90% (DMF)
Appearance: colorless oil
Package: 100g; 250g; 1Kg; 5Kg, bulk package
The chemical was firstly developed by Bredereck so that it also named as bis(dimethylamino)(tert-butoxy)methane. Since then, Bredereck's Reagent have been widely applied in many kinds of reactions:
preparation of pyrroloquinazolines as photochemotherapeutic agents
Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition
Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction
Aminomethylenation reactions
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